Argon
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| General |
| Name, Symbol, Number | Argon, Ar, 18 |
| Chemical series | Noble gases |
| Group, Period, Block | 18 (VIIIA), 3 , p |
| Density, Hardness | 1.784 kg/m3 (273 K), NA |
| Appearance | Colorless
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| Atomic Properties |
| Atomic weight | 39.948 amu |
| Atomic radius (calc.) | no data (71) pm |
| Covalent radius | 97 pm |
| van der Waals radius | 188 pm |
| Electron configuration | [Ne]33s2 3p6 |
| e- 's per energy level | 2, 8, 8 |
| Oxidation states (Oxide) | 0 (unknown) |
| Crystal structure | Cubic face centered |
| Physical Properties |
| State of matter | gas (nonmagnetic) |
| Melting point | 83.8 K (-308.7 °F) |
| Boiling point | 87.3 K (-302.4 °F) |
| Molar volume | 22.56 ×1010-3 m3/mol |
| Heat of vaporization | 6.447 kJ/mol |
| Heat of fusion | 1.188 kJ/mol |
| Vapor pressure | NA |
| Speed of sound | 319 m/s at 293.15 K |
| Miscellaneous |
| Electronegativity | no data (Pauling scale) |
| Specific heat capacity | 520 J/(kg*K) |
| Electrical conductivity | no data |
| Thermal conductivity | 0.01772 W/(m*K) |
| 1st ionization potential | 1520.6 kJ/mol |
| 2nd ionization potential | 2665.8 kJ/mol |
| 3rd ionization potential | 3931 kJ/mol |
| 4th ionization potential | 5771 kJ/mol |
| 5th ionization potential | 7238 kJ/mol |
| 6th ionization potential | 8781 kJ/mol |
| 7th ionization potential | 11995 kJ/mol |
| 8th ionization potential | 13842 kJ/mol |
| Most Stable Isotopes |
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| SI units & STP are used except where noted. |
Argon is a
chemical element in the
periodic table that has the symbol Ar and
atomic number 18. The third
noble gas, in period 8, argon makes up about 1% of the
Earth's atmosphere.
Notable Characteristics
Argon is 2.5 times as soluble in water as nitrogen which is approximately the same solubility as oxygen. This chemically inert element is colorless and odorless in both its liquid and gaseous forms. There are no known true chemical compounds that contain argon.
Applications
It is used in lighting since it will not react with the filament in a lightbulb even under high temperatures and other cases where diatomic nitrogen is an unsuitable (semi-)inert gas. Other uses;
- Used as an inert gas shield in arc welding and cutting,
- as a non-reactive blanket in the manufacture of titanium and other reactive elements,
- as a protective atmosphere for growing silicon and germanium crystals.
- Argon-39 has been used for a number of applications, primarily ice coring. It has also been used for ground water dating
Argon is also used in technical
SCUBA diving to inflate the drysuit, due to its nonreactive, heat isolating effect.
History
Argon (Greek argos meaning "lazy") was suspected to be present in air by
Henry Cavendish in
1785 but wasn't discovered until
1894 by
Lord Rayleigh and Sir
William Ramsay.
Occurrence
This gas is isolated through liquid air fractionation since the atmosphere contains only 0.94% argon. The
Martian atmosphere in contrast contains 1.6% of Ar-40 and 5
ppm Ar-36.
Isotopes
The main isotopes of argon found on earth are Ar-40, Ar-36, and Ar-38. Naturally occurring
K-40 with a
half-life of 1.250 x 10
9 years, decays to stable Ar-40 (11.2%) by
electron capture and by
positron emission, and also decays to stable Ca-40 (88.8%) by
negatron emission. These properties and ratios are used to determine the age of
rockss.
In earth's atmosphere, Ar-39 is made by cosmic ray activity, primarily with Ar-40. In the subsurface environment, it is also produced through neutron-capture by K-39 or alpha emission by calcium. Argon-37 is produced from the decay of calcium-40, the result of subsurface nuclear explosions. It has a half-life of 35 days.
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